Title page for etd-0830111-181102


[Back to Results | New Search]

URN etd-0830111-181102
Author Shin-Ying Yang
Author's Email Address No Public.
Statistics This thesis had been viewed 5331 times. Download 1013 times.
Department Chemistry
Year 2010
Semester 2
Degree Master
Type of Document
Language zh-TW.Big5 Chinese
Title Synthesis and Chracterization of Metal Complexes with N2S2 Coordination
Date of Defense 2011-07-27
Page Count 98
Keyword
  • Schiff base
  • thiolate
  • Zinc complex
  • coordination sphere
  • planarity
  • Nickel complex
  • Abstract In this study, we used different ways to synthetize four-coordinate
    zinc(II) and nickel(II) complexes with optically active Schiff base offering N2S2 coordination, i.e. N,N'-Bis(2-thiobenzylidene)-l,2-(R,R)cycholhexyl- enediaminatozinc(II) (1) and N,N'-Bis(2-thiobenzylidene)-l,2-(R,R)cychol-
    hexylenediaminatonickel(II) (2). We obtained the crystal structure of 2 and
    the pyridine adduct of 1, N,N'-Bis(2-thiobenzylidene)-l,2-(R,R)cycholhexylenediaminopyridylzinc(II) (1.Py). Coordination geometry around Zn atom in 1.Py is a distorted trigonal bipyramid. These structures were compared with the N2O2 stuctural analogues reported in the literature. We hope these chiral complexes can make contribution to the enzyme model studies in the future.
    Advisory Committee
  • Tsu-Hsin Chang - chair
  • Po-Chiao Lin - co-chair
  • Sodio Chin-Neng Hsus - co-chair
  • Michael Yen-Nan Chiang - advisor
  • Files
  • etd-0830111-181102.pdf
  • Indicate in-campus at 1 year and off-campus access at 1 year.
    Date of Submission 2011-08-30

    [Back to Results | New Search]


    Browse | Search All Available ETDs

    If you have more questions or technical problems, please contact eThesys