Title page for etd-0824111-113128


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URN etd-0824111-113128
Author Chin-yi Liao
Author's Email Address No Public.
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Department Electro-Optical Engineering
Year 2010
Semester 2
Degree Master
Type of Document
Language zh-TW.Big5 Chinese
Title The study of electrochemical deposited PANI thin film for polymer organic light emitting diodes
Date of Defense 2011-07-12
Page Count 105
Keyword
  • PANI
  • PLED
  • cyclic voltammetry
  • Abstract In this research,we used the electrochemical (cyclic voltammetry) method to synthesize (polyaniline) PANI thin film on the top of ITO substrate which applied extensively on polymer organic light emitting diodes based on ITO (170nm) / PANI (55nm ) / PFG(60 nm )/LiF(1nm)/Ca(10nm) / Al (200nm) .
    The PANI thin films have excellent optical and electric properties. According to the measurement results of ultraviolet visible spectrophotometry, the PANI thin films with different aniline monomer concentrations display the absorption peak at the range of 500nm to 600nm and have high light transmission near 90%. The conductivity of PANI thin film (2.02x10-2(s/cm)) is higher than that of PEDOT:PSS thin film (1.28x10-2(s/cm)). The highest occupied molecular orbital value of PANI thin film is about 5.0 eV that close to PEDOT:PSS thin film. Therefore, it is suitable act as hole transporting layer.
    In this study, we can control the surface morphology of PANI thin film by exchanging synthesized parameters. Finally, we have fabricated a PLED device with PANI as a hole transporting layer by electrochemical synthesis with at the aniline monomer concentration of 0.3M and the scan rate of 0.0.1 V/s. The device exhibits a maximum luminance of 10500 cd/m2 at 15 V and power efficiency of 0.25 lm/W at 10V.
    Advisory Committee
  • Ko-Shan Ho - chair
  • Chih-Chien Lee - co-chair
  • Yu-Kai Han - co-chair
  • Pin-Tsung Huang - co-chair
  • Mei-Ying Chang - advisor
  • Files
  • etd-0824111-113128.pdf
  • Indicate in-campus at 3 year and off-campus access at 3 year.
    Date of Submission 2011-08-24

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