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博碩士論文 etd-0818109-151315 詳細資訊
Title page for etd-0818109-151315
論文名稱
Title
高雄市愛河流域有機錫物種及其分布之研究
Studies of the Distribution and Species of Organotin in Love River of Kaohsiung City
系所名稱
Department
畢業學年期
Year, semester
語文別
Language
學位類別
Degree
頁數
Number of pages
105
研究生
Author
指導教授
Advisor
召集委員
Convenor
口試委員
Advisory Committee
口試日期
Date of Exam
2009-07-24
繳交日期
Date of Submission
2009-08-18
關鍵字
Keywords
有機錫、愛河
Love River, organotin
統計
Statistics
本論文已被瀏覽 5787 次,被下載 1674
The thesis/dissertation has been browsed 5787 times, has been downloaded 1674 times.
中文摘要
愛河,全長十二公里,是高雄的第一大河。然而,通過高雄港與海洋相接所帶來的卻是潛藏的生態危機。高雄港有來自世界各地的貨櫃船往來頻繁,且港內有數個造船廠、修船場和漁港,因此港內有機錫化合物的汙染十分嚴重,而愛河河口即位於高雄港,且感潮帶長,受高雄港海水污染可能性相當高;上游河段之家庭、工業及農業廢水的排放,亦可能造成愛河有機錫化合物的汙染。
本研究分別於乾、雨季採集愛河主流下游表、底層及愛河沿岸的水樣,並採集愛河沿岸表層沉積物及高雄橋、中正橋的柱狀沉積物,以NaBEt4 衍生,並利用GC-FPD進行有機錫化合物的含量分析。
經分析結果顯示,愛河水樣中MBT 含量為8.2–25.0 ng/L as tin,DBT 為3.3–17.1 ng/L as tin,TBT 為ND–9.1 ng/L as tin;表層沉積物中MBT 含量為12.5-69.2 ng/g as tin,DBT 為7.1-31.2 ng/g as tin,TBT 為ND-22.6 ng/g as tin。愛河下游河段受有機錫化合物汙染的趨勢為高雄橋往水中閘門趨於緩和;上游的河堤社區廢水汙染較嚴重,造成在裕誠橋附近有一汙染高峰。
以沉積物之垂直分布來看,MBT 含量高達61.2-273.2 ng/g as tin,DBT 達22.8-256.2 ng/g as tin,TBT 達8.6-168.4 ng/g as tin,表示愛河早期受有機錫化合物的汙染相當嚴重。此外,本研究所分析的有機錫物種中,並未檢測出苯基錫含量,愛河樣品中主要以丁基錫汙染為主。
與往年相比,現今愛河受有機錫化合物污染的情形已大幅減輕,但仍需持續關心,以降低污染所可能帶來的生態危機。
Abstract
Love River, 12 km in length from inland to the sea, is the longest river in Kaohsiung. Love River passes through the harbor of Kaohsiung and connects with the sea bring hidden ecological crises. Because there are persistent shipping from the whole world, several shipyards and fishing ports in the harbor of Kaohsiung, the pollution of organotin is very serious in the harbor area. It’s possible that Love River may be polluted by the seawater from the harbor of Kaohsiung for the long intertidal zone and the estuary, in the harbor of Kaohsiung. Upstream sections may be also polluted by organotin compounds from domestic, industrial and agricultural wastewater.
This study is not only collecting the surface and bottom riverwater during winter and summer, but also sampling the sediments in Love River. These samples are derivated with NaBEt4 and analyzed the concentration of organotin by gas chromatograph with a flame photometric detector.
The results reveal that concentrations of MBT are 8.2-25.0 ng/L as tin, DBT are 3.3-17.1 ng/L as tin, TBT are 4.3-9.1 ng/L as tin in the riverwater. The concentrations of MBT are 12.5-69.2 ng/g as tin, DBT are 7.1-31.2 ng/g as tin, TBT are 15.8-22.6 ng/g as tin in the surface sediments. The pollution of organotin decrease from the harbor of Kaohsiung to the water gate in the downstream. A peak of pollution is found near the Yu-Cheng bridge in the upstream.
The concentrations of the vertical distribution of sediments, MBT are as high as 61.2-273.2 ng/g as tin, DBT are 22.8-256.2 ng/g as tin, TBT are 8.6-168.4 ng/g as tin, it indicates that Love River was polluted extremely seriously by organotin compounds in the past. However, phenyltin compounds were not detected in these samples.
As compared with previous reports, today the pollution of organotin compounds has been greatly reduced in Lover River. But it remains to be cared in order to reduce the potential ecological crises which are brought by the pollution.
目次 Table of Contents
中文摘要 I
英文摘要 III
目錄 V
表目錄 VII
圖目錄 VIII

壹、前言 1
一、有機錫化合物的種類與特性 1
二、有機錫化合物的用途與污染 1
三、有機錫化合物進入環境之途徑及流佈 7
(一) 船舶防污漆之溶出 7
(二) 工業廢水之排放 7
(三) 農業和都市廢水 11
四、有機錫化合物之毒性及管制 13
五、愛河簡介 17
六、研究動機 18

貳、材料與方法 20
一、藥品與溶液製備 20
(一) 藥品部分 20
(二) 試劑水 21
(三) 試藥配製 21
二、儀器設備與實驗器材 22
三、樣品採集與處理方法 23
(一) 採樣地點 23
(二) 採樣時間 23
(三) 採樣方法與樣品前處理 25
四、分析方法 25
(一) 水樣中有機錫化合物之分析方法 25
(二) 沉積物中有機錫化合物之分析方法 26
(三) 檢量線製作 26
(四) 方法偵測極限 30
(五) 回收率 30


參、結果與討論 32
一、有機錫分析 32
(一) 實驗分析方法 32
(二) 層析圖譜 32
(三) 檢量線的製作 34
(四) 數據處理 34
(五) 方法偵測極限 34
(六) 回收率 41
二、水樣部份 41
(一) 溫度 41
(二) 鹽度 41
(三) pH 值 48
(四) 水樣中有機錫濃度分布 48
1. 乾季 48
2. 雨季 52
三、沉積物部份 63
(一) 表層沉積物中有機錫濃度分布 63
(二) 高雄橋、中正橋沉積物有機錫濃度之垂直分布 66

肆、結論 72

伍、參考文獻 73

附錄一、原始數值 81
附錄二、沉積物檢量線配置方法 92


參考文獻 References
中央氣象局 http://www.cwb.gov.tw/V6/index.htm

行政院環境保護署編印,1992,環境影響評估相關法規彙編:水體分類與水質標準,536-539。

林衍孜,2006,台灣高屏地區港口底質中有機錫化合物分布之研究,國立中山大學碩士論文。

紀則賢,2004,高雄愛河流域有機錫分布之研究,國立中山大學碩士論文。

唐川禾,2007,鹿耳門溪及四草漁港環境及生物體中有機錫之研究,國立中山大學博士論文。

徐天琦,2003,有機錫對高雄港區毛蝦之毒性研究,國立中山大學碩士論文。

高雄市政府工務局下水道工程處, 97愛河治平橋至鼎新橋流域水質水文監測暨水質改善委託技術服務案之調查報告。

張貴能,2004,高雄港區有機錫分布及其污染史之研究,國立中山大學碩士論文。

經濟部網站http://www.moea.gov.tw/

劉莉蓮,1997。在有機錫污染下淡水田螺和椎時螺基因型及外表型反應之比較,行政院國家科學委員會專題研究計畫成果報告。

Alzieu, C.L., Sanjuan, J., Deltreil, J.P. and Borel, M., 1986. Tin contaimination in Arcachon Bay : effects on oyster shell anomalies, Mar. Pollut. Bull., 17 : 494-498.

Bancon-Montigny, Ch., Lespes, G. and Potin-Gautier, M., 2004. Organotin survey in the Adour–Garonne basin. Water Res., 38 : 933–946

Berto, D., Giani, M., Boscolo, R., Covelli, S., Giovanardi, O., Massironi, M. and Grassia, L., 2007. Organotins (TBT and DBT) in water, sediments, and gastropods of the southern Venice lagoon (Italy). Mar. Pollut. Bull.,55 : 425-435

Byran, G. W. and Gibbs, P.E., 1988. A comparison of the effectiveness of tri-n-butyltin chlorides compounds in promoting the development of imposex in the dogwhelk nucella lapillus. J. Mar. Biol. Ass., 68 : 733-733.
Cardellicchio, N., Geraci, S., Marra, C. and Paterno, P., 1992. Determination of tributyltin oxide in coastal marine sediments and mussels by electrothermal atomic absorption spectrometry, Appl. Organomat. Chem., 6:241-246.

Cardwell, R.D. and Sheldon, A. W., 1986. A risk assessment concerning
the fate and effects of tributyltins in the environment. Oceans,
1117-1129.

Ceulemans, M. and Adams, F.C., 1995. Evaluation of sample preparation
methods for organotin speciation analysis in sediments- focus on
monobutyltin extraction. Anal. Chim. Acta., 317 : 161-170.

Craig, P. J., 1986. Organometallic compounds in the environment-
principles and reaction, John Wiley & Sons, New York.

deMora, S. J., Stewart, C. and Philips, D., 1995. Sources and rate of degradation of tri(n-butyl)tin in marine sediments near Auckland, New
Zealand. Mar. Pollut. Bull., 30 : 50-57.

Diez, S., Abalos, M. and Bayona, J. M., 2002. Organotin contamination in sediments from the western mediterranean enclosures following 10 years of TBT regulation. Water Res., 36 : 905-918.


Diez, S., Lacorte, S., Viana, P., Barcelo, D., Bayona, J. M., 2005. Survey of organotin compounds in rivers and coastal environments in Portugal 1999-2000. Environ. Pollut,. 136 : 525-536.

Dong, C. D., Chen, C. W. and Liu, L. L., 2004. Seasonal variation in the composition and concentration of butyltin compounds in marine fish of Taiwan. Environ. Pollut., 131: 509-514.

Dowson, P. H., Bubb, J. M., Lester, J. N. 1993. Depositional profiles and relationships between organotin compounds in freshwater and estuarine sediment cores. Environ. Monit. Assess., 28 : 145-160.

Evans, C. J. and Karpel, S., 1985. Organotin Compounds in modern technology, Elsevier Science Publisher, Amsterdam.

Fent, K., 1996. Ecotoxicology of organotin compounds. Crit. Rev.Toxicol., 26: 1-117.

Gomez-Ariza, J. L., Morales, E. and Giraldez, I., 1998. Spatial distribution of butyltin and phenyltin compounds on the Huelva coast (Southwest Spain). Chemosphere., 37 : 937-950.

Harino, H., Fukushima, M., Kurokawa, Y. and Kawai, S., 1998. Degradation of the tributyltin compounds by the bacteria in water and sediment collected from harbor area of Osaka city in Japan. Environ. Pollut., 98 : 163-167.
Hoch, M., 2001. Organotin compounds in the environment-an overview. Appl. Geochem., 16, 719-743.

Huaa, J. and Liu, S. M., 2007. Butyltin in ballast water of merchant ships. Ocean. Eng., 34 : 1901-1907.

Huggett, R. J., Unger, M. A., Seligman, P. F. and Valkirs A . O., 1992. The marine biocide tributyltin- assessing and managing the environmental risks. Environ. Sci. Technol ., 26 : 233-237.

Jarvinen, A. W., Tanner, D. K., Kline, E. R. and Knuth, M. L., 1988. Acute and chronic toxicity of triphenyltin hydroxide to fathead minnow (pimephales promelas) following brief or continuous exposure. Environ. Pollut., 52 : 289-301.

Quevauviller, Ph., Bruchet, A. and Donard, O. F. X. 1991. Leaching of organotin compounds from poly(vinyl chloride) (PVC) material. Appl. Organometal. Chem., 5 : 125-129.

Kannan, K., Corsolini, S., Forcardi, F., Tanabe, S. and Tatsukawa R., 1996. Accumu lation pattern of butyltin compounds in dolphin, tuna and shark collected from Italian coastal waters. Arch. Environ. Con. Tox., 31 : 19-23.



Kawai, S., Kurokawa, Y., Harino, H., Fukushima, M., 1998. Degradation of tributyltin by a bacterial strain isolated from polluted river water. Environ. Pollut., 102:259-263.

Ko, M. M. C., Bradley, G. C., Neller, A. H. and Broom, M. J., 1995.
Tributyltin contamination of marine sediment of Hong Kong. Mar. Pollut. Bull., 31:249-253.

Lee, C. C., Hsieh, C. Y. and Tien, C. J., 2006. Factors influencing organotin distribution in different marine environmental compartments, and their potential health risk. Chemosphere., 65:547-559.

Maguire, R. J., Carey, J. H. and Hale, E. J., 1983. Degradation of tri-n-butyltin species in water. J. Agric. Food Chem., 31: 1060-1065.

Maguire, R. J. and Tkacz, R. J., 1985. Degradation of the tri-n-butyltin species in water and sediment from Toronto harbor. J. Agric. Food Chem. , 33 : 947-953.

Montigny, C., Lespes, G. and Potin-Gautier, M., 1998. Matrix effect and selectivity of the detector in the determination of butyl- and phenyltins by gas chromatography-flame photometric detection. J. Chromatography A., 819 : 221-230.


Mzoughi, N., Lespes, G., Bravo, M., Dachraoui, M. and Potin-Gautier, M., 2005. Organotin speciation in Bizerte Lagoon (Tunisia). Sci. Total Environ., 349 : 211-222.

Sadiki, A., Williams, D.T., Carrier, R. and Thomas, B., 1996. Pilot study on contamination of drinking water by organotin compounds from PVC material. Chemosphere., 32 : 2389-2398.

Shim, W. J., Oh, J. R., Kahng, S. H., Shim, J. H. and Lee, S. H., 1999. Horizontal distribution of butyltins in surface sediments from an enclosed bay system, Korea. Environ. Pollut., 106 : 351-357.

Sun, H., Huang, G. and Dai, S., 1996. Adsorption behavior and studies of organotin compounds on Estuarine sediment. Chemosphere., 33:831-838.

Terlizzi, A., Fraschetti, S., Gianguzza, P., Faimali, M. and Boero, F., 2001. Environmental impact of antifouling technologies: state of the art and perspectives, aquatic conserv. Mar. Freshw. Ecosyst., 11: 311-317.


Valkirs, A. O., Seligman, P. F., Stang, P. M. and Homer, V., 1986. Measurement of butyltin compounds in San Diego bay, Mar. Pollut. Bull., 17 : 319-324.

Walsh, G.E., McLaughlan, L.L., Louie, M. K. and Deans, C.H., 1985. Effect of organotins on growth and survival of two marine diatoms, skeletonema costatum and thalassira pseudonana. Chemosphere., 14 : 383-392.

Whalen, M. M., Loganathan, B. G. and Kannan, K., 1999. Immunotoxivity of environmentally relevant concentration of butyltin on human nayural killer cells in Vitro. Environ. Res., 81 : 108-116.

Whalen, M. M., Walker, L. and Loganathan, B. G., 2002. Interleukis 2 and 12 produce significant recovery of cyotoxic function in dibutyltin -exposure human natural killer cells. Environ. Res. Sec. A., 88 : 103-115.

Yamabe, Y. and Hoshino, A., 2000. Enhancement of angrogen -dependent transcription and cell proliferation by tributyltin and triphenyltin in human prostate cancer cell. Toxic. App. Pharm., 169 : 177-184.
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