URN etd-0809111-225407 Author Yu-Huei Song Author's Email Address email@example.com Statistics This thesis had been viewed 5572 times. Download 513 times. Department Chemistry Year 2010 Semester 2 Degree Master Type of Document Language zh-TW.Big5 Chinese Title (一) Photolytic Study of 2-Azido-1-(2-pyridinyl)ethan- one and Its Derivatives
(二) Pyrolytic Study of 2-(Azidomethyl)pyridine and Its Derivatives
(三) Pyrolytic Study of 2-Cyclohexeno[b]furylmethyl Benzoate
Date of Defense 2011-07-18 Page Count 276 Keyword photolysis flash vacuum pyrolysis Cyclohexeno[b]furylmethyl Azidomethyl Azidoethanone Abstract 一. Photolysis of 2-azido-1-(2- pyridyl)ethanone (68),2-azido-1-(3-pyridyl)ethanone)
(69),2-azido-1-(1-methyl-2-pyrryl)ethanone (53) and 2-azido-1-(1-methyl-3-indo yl)ethanone gave Norrish products (71, 7 3-76), (84-86, 89), (92-94) and (93, 95-98).
二. Pyrolysis of 2-(azidomethyl)pyridine (9) and 4-(azidomethyl)pyr idine (10) gave the expected products 1,3,5-tri-2-pyridyl-2,4-diaza-1,4-pentadiene (13) and 1,3,5-tri-4-pyridyl-2,4-diaza-1,4-pentadiene (21).
三. Pyrolysis of 2-cyclohexeno[b]furylmethyl benzoate (31) gave 2-methylbenzo[b]-
furan (40) and benzene products.
Advisory Committee Cherng-Chyi Tzeng - chair
none - co-chair
Yeh-Long Chen - co-chair
Chin-Hsing CHOU - advisor
Indicate in-campus at 0 year and off-campus access at 1 year.
etd-0809111-225407.pdf Date of Submission 2011-08-09