Title page for etd-0728117-144500


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URN etd-0728117-144500
Author Hsuan-Ying Hung
Author's Email Address No Public.
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Department Chemistry
Year 2016
Semester 2
Degree Master
Type of Document
Language zh-TW.Big5 Chinese
Title Synthesis and Characterization of the Unsymmetrical
N-aryl-N'-alkylpyridyl β-Diketiminato Nickel(II) and Copper(II) Complexes
Date of Defense 2017-07-26
Page Count 132
Keyword
  • Nickel(II)
  • (I) Complexes
  • Copper(II) Complexes
  • NO2-
  • CO
  • β-Diketiminato
  • Abstract The activation and transformation of small-molecule such as N2, NO2, O2, CO, H2, or methane gas is an important area of chemical research. Many types of metalloenzymes have well fuction and playe a key role in small-molecule activation. Scientists try to prepare low molecule weight model compounds to mimic and study the detail mechanisms of biological small-molecule activation. Our lab is interesting in model complexes of nickel-containing and copper-containing enzymes.
      N, N’-aryl substituted β-diketiminato type ligands can be as sterically crowded spectator ligands to stabilize coordinately unsaturated metal centers in coordination. To explore the coordination chemistry on the bio-inspired nickel and copper compounds, we synthesize a series of N-aryl-N’-alkylpyridyl substituted β-diketiminato nickel and copper complexes and test their reactivity toward to NO2-, O2 and CO. Those complexes have been synthesized and characterized by 1H NMR, ESI-MS, and UV-vis spectroscopy as well as single-crystal X-ray diffractometry.
    Advisory Committee
  • Hsuan-Ying Chen - chair
  • Ming-Li Tsai - co-chair
  • Sodio C. N. Hsu - co-chair
  • Michael Yen-Nan Chiang - advisor
  • Files
  • etd-0728117-144500.pdf
  • Indicate in-campus at 5 year and off-campus access at 5 year.
    Date of Submission 2017-08-28

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