Title page for etd-0725105-172412


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URN etd-0725105-172412
Author Chun-Hung Chou
Author's Email Address s872236@yahoo.com.tw
Statistics This thesis had been viewed 5332 times. Download 1392 times.
Department Chemistry
Year 2004
Semester 2
Degree Master
Type of Document
Language zh-TW.Big5 Chinese
Title Syntheses and structures of copper(I) dinuclear and polynuclear complexes containing phosphorous- and nitrogen- donor ligands
Date of Defense 2005-07-13
Page Count 138
Keyword
  • Macrocyclemolecule
  • Self-assembly supramolecule
  • Phosphine ligand
  • Copper(I) complex
  • Abstract Here we report the preparation, structure, and spectroscopic properties of an intriguing copper(I) cyclophane-like dimeric complex [Cu2(dppa)2(bpy)2][BF4]2(2)、[Cu2(dppa)2(mbpy)2][BF4]2(3)、[Cu2(dpbp)2(bpy)2][BF4]2(7)和[Cu2(dppb)2(bpy)2] [BF4]2(8), containing phenyl phosphine bridge ligands, such as diphenylphosphino acetylene (dppa), 1,4-bis(diphenylphosphino)benzene (dppb) and 4,4'-bis(diphenyl phosphino)biphenyl (dpbp). As a building unit, the complex [Cu2(dpbp)2(NCMe)4] [BF4]2(9) containing labile acetonitrile molecules those can be easily substituted by anionic ligands, is expected to combine with suitable linkers to synthesize supramolecular arrays with shapes of polygons and polyhedra.
    Advisory Committee
  • none - chair
  • Tsu-Hsin Chang - co-chair
  • Wen-Yann Yeh - advisor
  • Files
  • etd-0725105-172412.pdf
  • indicate access worldwide
    Date of Submission 2005-07-25

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