Title page for etd-0630113-150246


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URN etd-0630113-150246
Author Yu-fang Lin
Author's Email Address No Public.
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Department Chemistry
Year 2012
Semester 2
Degree Master
Type of Document
Language zh-TW.Big5 Chinese
Title Reactions of Open-Cage Fullerene with Triruthenium Carbonyl Cluster
Date of Defense 2013-07-25
Page Count 91
Keyword
  • Fullerene
  • Open-Cage Fullerene
  • Triruthenium Carbonyl Cluster
  • Abstract Reaction of C80H14N2O2 (2) and Ru3(CO)12 in refluxing chlorobenzene affords Ru3(CO)8(μ2, η7-(C63NO2Ph2Py)) (3). Compound 3 apparentily arises from C-C bond activation of 2 to generate an diol ligand bridging motif. In contrast, compound 4 is produced by C-H / C-O activation insertion of one ruthenium atom into a pentagonal ring of 3, together with the Ru3 cluster fragmentation. Complexes 3 and 4 have been characterized by IR, NMR, UV-Vis, CV, Mass spectroscopies, and single-crystal X-ray diffraction study.
    Advisory Committee
  • Michael Yen-Nan Chiang - chair
  • Sodio C. N. Hsu - co-chair
  • Wen-Yann Yeh - advisor
  • Files
  • etd-0630113-150246.pdf
  • Indicate in-campus at 2 year and off-campus access at 2 year.
    Date of Submission 2013-07-30

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