Title page for etd-0626116-223729


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URN etd-0626116-223729
Author Yi-Min Lin
Author's Email Address No Public.
Statistics This thesis had been viewed 5341 times. Download 276 times.
Department Chemistry
Year 2015
Semester 2
Degree Master
Type of Document
Language zh-TW.Big5 Chinese
Title Reactions of Open-Cage Fullerene with Molybdenum Carbonyl Complex
Date of Defense 2016-07-14
Page Count 74
Keyword
  • Fullerene
  • Molybdenum Carbonyl Complex
  • Open-Cage Fullerene
  • Abstract Reaction of C80H14N2O2(2’) with Mo(CO)6 in refluxing chlorobenzene, produced Mo(CO)3η4-(C63NPh2Py) (3). Compound( 3) occurred C=O bond activation, than the diketone group ligand eliminated two oxygen atoms to generate the olefin, which mimics the organic McMurry reaction. Complex (3) has been characterized by IR, NMR, Mass spectroscopy, and single-crystal、X-ray diffraction study.
    Advisory Committee
  • Sodio C. N. Hsu - chair
  • Hsung-Ying Chen - co-chair
  • Wen-Yann Yeh - advisor
  • Files
  • etd-0626116-223729.pdf
  • Indicate in-campus at 1 year and off-campus access at 1 year.
    Date of Submission 2016-07-27

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