Title page for etd-0604115-140952


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URN etd-0604115-140952
Author Meng-fan Chiang
Author's Email Address No Public.
Statistics This thesis had been viewed 5352 times. Download 384 times.
Department Chemistry
Year 2014
Semester 2
Degree Master
Type of Document
Language zh-TW.Big5 Chinese
Title Palladium-Catalyzed Direct Ortho-Aroylation of N-Arylpyridin-2-amines with Aldehydes via C-H Activation
Date of Defense 2015-06-22
Page Count 344
Keyword
  • palladium
  • C-C coupling
  • C-H activation
  • catalyzed reaction
  • ortho-aroylation
  • Abstract A direct ortho-aroylation of N-arylpyridin-2-amines with aldehydes to afford mono- and di-aroylated N-arylpyridin-2-amines in modest to good yields is presented. In the reaction, palladium(II) acetate, tert-butyl hydroperoxide (TBHP), and 1,4-dioxane were used as the catalyst, oxidant, and solvent, respectively. The synthetic methodology serves good functional group compatibility. A possible catalytic mechanism is also presented.
    Advisory Committee
  • Po-Chiao Lin - chair
  • Jen-Chieh Hsieh - co-chair
  • Ming-Jung Wu - advisor
  • Files
  • etd-0604115-140952.pdf
  • Indicate in-campus at 2 year and off-campus access at 2 year.
    Date of Submission 2015-07-04

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