| URN |
etd-0204108-115520 |
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| Author |
Shu-fan Lin |
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| Author's Email Address |
No Public. |
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| Statistics |
This thesis had been viewed 5574 times. Download 1459 times. |
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| Department |
Chemistry |
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| Year |
2007 |
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| Semester |
1 |
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| Degree |
Ph.D. |
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| Type of Document |
|
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| Language |
zh-TW.Big5 Chinese |
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| Title |
The Application of Molecular Wire-Like Ruthenium Complexes Containing Polyferrocenyl-Ethynyl as a spacer |
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| Date of Defense |
2007-10-23 |
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| Page Count |
111 |
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| Keyword |
ferrocene
molecular wire
electrochemistry
ruthenium
mixed-valence
|
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| Abstract |
The preparations of multinuclear supramolecules assembled from ethynylferrocene(s) redox-active subunit end-capping with [(η5-C5H5)(dppe)Ru] metal centers are described. Electrochemical measurements indicate that ferrocenyl-ethynyl spacers appear to be promising spacers which can ensure fast and quantitative transfer of information between two Ru2+ metal centers. |
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| Advisory Committee |
Chin-Hsing Chou - chair
Tsu-Hsing Chang - co-chair
Liang-Shiu Lee - co-chair
Hsiu-Wei Chen - co-chair
Teng-Yuan Dong - advisor
|
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| Files |
indicate accessible in a year |
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| Date of Submission |
2008-02-04 |
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